Next we go to the small scale of mechanicaloscillation. This time we take a sodium chloride crystal, which has sodium ionsand chlorine ions next to each other, as we described in an early chapter.These ions are electrically charged, alternately plus and minus. Now there isan interesting oscillation possible. Suppose that we could drive all the pluscharges to the right and all the negative charges to the left, and let go; theywould then oscillate back and forth, the sodium lattice against the chlorinelattice. How can we ever drive such a thing? That is easy, for if we apply anelectric field on the crystal, it will push the plus charge one way and theminus charge the other way! So, by having an external electric field we canperhaps get the crystal to oscillate. The frequency of the electric fieldneeded is so high, however, that it corresponds to infrared radiation!So we try to find a resonance curve by measuring the absorption of infraredlight by sodium chloride. Such a curve is shown in Fig. 23–7. Theabscissa is not frequency, but is given in terms of wavelength, but that is justa technical matter, of course, since for a wave there is a definite relationbetween frequency and wavelength; so it is really a frequency scale, and acertain frequency corresponds to the resonant frequency.
下面,我们来看,小尺度的力学震荡。这次,我们取一个钠氯晶体,它有钠离子和氯离子,挨在一起,正如在前面某章,我们所描述。这些离子,是带电的,交替地带正电和负电。现在,一个有趣的震荡,就是可能的。假设我们可以把所有的正电荷,都拉到右边,所有的负电荷,都拉到左边,然后,让它们开始运动;它们就会前后震荡,钠栅格,相对于氯栅格。我们如何驱动这样一个事情呢?很容易,因为,如果我们把电场,应用到晶体上,它将会把正电荷推向一边,负电荷推向另一边!于是,通过有一个外部的电场,我们或许就可以让晶体去振荡。然而,所需的电场频率,非常高,以至于,相当于是红外辐射!所以我们尝试,通过测量红外线被钠氯化合物所吸收,来找到一条共振曲线。这种曲线如图23-7。横坐标不是频率,而是波长,但这只是一个技术问题,当然,由于对一个波来说,在频率和波长之间,有确定的关系;所以,它确实是一个频率尺度,某确定频率,相应于共振的频率。

Fig. 23–7.Transmission of infrared radiationthrough a thin (0.17 μ m) sodium chloride film. [After R. B. Barnes, Z. Physik 75,723 (1932). Kittel, Introduction to Solid State Physics, Wiley, 1956.] 图23-7 红外辐射穿过一个薄膜(0.17 μm),薄膜由钠和氯化物构成。[在R. B. Barnes之后, Z. 物理学 75, 723 (1932). Kittel, 《固体物理学介绍》, Wiley出版社, 1956.]
下面,我们来看,小尺度的力学震荡。这次,我们取一个钠氯晶体,它有钠离子和氯离子,挨在一起,正如在前面某章,我们所描述。这些离子,是带电的,交替地带正电和负电。现在,一个有趣的震荡,就是可能的。假设我们可以把所有的正电荷,都拉到右边,所有的负电荷,都拉到左边,然后,让它们开始运动;它们就会前后震荡,钠栅格,相对于氯栅格。我们如何驱动这样一个事情呢?很容易,因为,如果我们把电场,应用到晶体上,它将会把正电荷推向一边,负电荷推向另一边!于是,通过有一个外部的电场,我们或许就可以让晶体去振荡。然而,所需的电场频率,非常高,以至于,相当于是红外辐射!所以我们尝试,通过测量红外线被钠氯化合物所吸收,来找到一条共振曲线。这种曲线如图23-7。横坐标不是频率,而是波长,但这只是一个技术问题,当然,由于对一个波来说,在频率和波长之间,有确定的关系;所以,它确实是一个频率尺度,某确定频率,相应于共振的频率。

Fig. 23–7.Transmission of infrared radiationthrough a thin (0.17 μ m) sodium chloride film. [After R. B. Barnes, Z. Physik 75,723 (1932). Kittel, Introduction to Solid State Physics, Wiley, 1956.] 图23-7 红外辐射穿过一个薄膜(0.17 μm),薄膜由钠和氯化物构成。[在R. B. Barnes之后, Z. 物理学 75, 723 (1932). Kittel, 《固体物理学介绍》, Wiley出版社, 1956.]




(24.2)
(24.6)
(24.7)








