We shall next discuss the characteristicsof molecular forces. These are forces between the atoms, and are the ultimateorigin of friction. Molecular forces have never been satisfactorily explainedon a basis of classical physics; it takes quantum mechanics to understand themfully. Empirically, however, the force between atoms is illustratedschematically in Fig. 12–2, wherethe force F between two atoms is plotted as a function of the distance rbetween them. There are different cases: in the water molecule, forexample, the negative charges sit more on the oxygen, and the mean positions ofthe negative charges and of the positive charges are not at the same point; consequently,another molecule nearby feels a relatively large force, which is called adipole-dipole force. However, for many systems the charges are very much betterbalanced, in particular for oxygen gas, which is perfectly symmetrical. In thiscase, although the minus charges and the plus charges are dispersed over the molecule,the distribution is such that the center of the minus charges and the center ofthe plus charges coincide. A molecule where the centers do not coincide iscalled a polar molecule, and charge times the separation between centers iscalled the dipole moment. A nonpolar molecule is one in which the centers ofthe charges coincide. For all nonpolar molecules, in which all the electricalforces are neutralized, it nevertheless turns out that the force at very largedistances is an attraction and varies inversely as the seventh power of thedistance, or F=k/r7 , where k is a constant that depends on the molecules. Why this is we shalllearn only when we learn quantum mechanics. When there are dipoles the forcesare greater. When atoms or molecules get too close they repel with a very largerepulsion; that is what keeps us from falling through the floor!
下面我们讨论分子力的特性。这些力是原子间的力,是摩擦的终极起源。分子力从来没有在经典物理学的基础上,得到过满意的解释。然而,根据经验,原子间的力,可以大致地图示,见图12-2,这里,两个原子之间的力F被当作它们之间距离r的函数。还有些不同的情况:例如,在水分子中,负电荷更偏于氧原子,负电荷与正电荷的平均位置,并不在同一个点上;所以,附近的另外一个分子,就会感到相对较大的力,这被称为偶极子-偶极子的力。然而,对于很多系统来说,电荷还是比较好地被平衡了,特别是对氧气,它是完全对称的。在这种情况下,虽然负电荷和正电荷被散布在分子中,这种分布是这样的,负电荷的中心与正电荷的中心,是重合的。一个分子,它的中心如果不重合,就被称为极性分子,而电荷乘以两个中心之间的距离,被称为偶极矩。一个非偶极的分子呢,就是中电荷中心重合的分子。一个非极性的分子,就是在其中,电荷的中心是重合的分子。对于所有的非极性分子来说,尽管在其中,所有的电力都被中和了,但结果则是,在很大的距离上的力,是吸引力,且反比于距离的7次方,或者F=k/r7,这里,k是一个常数,依赖于分子。为什么会是这样,只有当我们学习电动力学时,才能学到。当有偶极子时,力就会更大些。当原子或分子变得太近时,它们就会用一个很大的力,相互排斥;我们不会从地板上掉下去,就是因为它托着。
下面我们讨论分子力的特性。这些力是原子间的力,是摩擦的终极起源。分子力从来没有在经典物理学的基础上,得到过满意的解释。然而,根据经验,原子间的力,可以大致地图示,见图12-2,这里,两个原子之间的力F被当作它们之间距离r的函数。还有些不同的情况:例如,在水分子中,负电荷更偏于氧原子,负电荷与正电荷的平均位置,并不在同一个点上;所以,附近的另外一个分子,就会感到相对较大的力,这被称为偶极子-偶极子的力。然而,对于很多系统来说,电荷还是比较好地被平衡了,特别是对氧气,它是完全对称的。在这种情况下,虽然负电荷和正电荷被散布在分子中,这种分布是这样的,负电荷的中心与正电荷的中心,是重合的。一个分子,它的中心如果不重合,就被称为极性分子,而电荷乘以两个中心之间的距离,被称为偶极矩。一个非偶极的分子呢,就是中电荷中心重合的分子。一个非极性的分子,就是在其中,电荷的中心是重合的分子。对于所有的非极性分子来说,尽管在其中,所有的电力都被中和了,但结果则是,在很大的距离上的力,是吸引力,且反比于距离的7次方,或者F=k/r7,这里,k是一个常数,依赖于分子。为什么会是这样,只有当我们学习电动力学时,才能学到。当有偶极子时,力就会更大些。当原子或分子变得太近时,它们就会用一个很大的力,相互排斥;我们不会从地板上掉下去,就是因为它托着。










