http://v2smutstone.wikia.com/wiki/Smutstone_Wiki

10 - Level up a Red card
20 - Win Duels 5 times
30 - Win City 16.2
40 - Seduce Red cards 3 times (they can be three different cards)
50 - Open Boxes 4 times (bronze, silver or golden boxes)
60 - Level up Red cards 5 times
70 - Win Forest 5
80 - Win Duels 10 times
90 - Win Forest 9.2
100 - Get 10 Rare Red card duplicates
110 - Open chests in Duels 4 times
120 - Win Forest 10.2
130 - Get 20 Common Red card duplicates
140 - Open Baby Jack Coffer
150 - Reach Masters League I in Duels
160 - Get 2 Epic Red Card duplicates
170 - Level up Red cards 10 times
180 - Win Forest 14.3
190 - Open chests in Duels 8 times
200 - Open Jack Coffer
210 - Get 5 Epic Red card duplicates
220 - Reach Master League 2
230 - Get 2 Legendary Red card duplicates
240 - Get 20 Rare Red card duplicates
250 - Seduce any cards 5 times
260 - Spend 2000 Pumpkins
270 - Reach Master League 3 in Duels
280 - Level up Epic Red cards 10 times
290 - Win Sands 4.5
300 - Reach Champion League I in Duels
310 - Have 3-star Butcher or Traveler card
320 - Have 4-star Epic Red card
330 - Win Sands 9.2
340 - Reach Champion League 2 in Duels
350 - Have 3-star Red Witch or Crow Girl card
360 - Have Seer card
370 - Get 7 Legendary Red card duplicates
380 - Win Sands 12.1
390 - Reach Champion League 3 in Duels
400 - Open Jack Coffer 3 times
410 - Win a prize in the Halloween Tournament
420 - Open Baby Jack Coffer 5 times
430 - Win Sands 13.2
440 - Reach Legendary League I in Duels
450 - Open Silver Box 15 times
460 - Level up Red cards 15 times
470 - Get 10 Legendary Red card duplicates
480 - Have Vengeance Spirit card
490 - Reach Legendary League II in Duels
500 - Gather 6 cards and get 7th card (End of Path)